New chlorine-carboxylate complexes of rhenium(III) with alkylcarboxylate with high steric hindrance

Nowe chlorkowo-karboksylanowe kompleksy renu(III) z alkilokarboksylanem o dużej zawadzie przestrzennej

 

TITLE  New chlorine-carboxylate complexes of rhenium(III) with alkylcarboxylate with high steric hindrance
DESCRIPTION OF THE SOLUTION A new chloride-carboxylate complex of rhenium(III) with an alkylcarboxylate with a large spatial hinge and small-molecule ligands with the general formula cis-[(Re2Cl4(CH3OH)(DMSO)(µ-O2CCH2tBu)2]CH3OH. Also the subject of the invention is a new chloride-carboxylate complex of rhenium(III) with alkylcarboxylate with a large spatial hinge and small-molecule ligands with the general formula cis-[Re2Cl4(DMSO)2(µ-O2CCHEt2)2]. The subject of the invention is also a new chloride-carboxylate complex of rhenium(III) with alkylcarboxylate with a large spatial hare with the general formula trans-[Re2Cl2(µ-Cl2)(µ-O2CCH2tBu)2]n. Also the subject of the invention is a new chloride-carboxylate complex of rhenium(III) with an alkylcarboxylate with a large spatial hare with the general formula trans-[Re2Cl4(µ-O2CCHEt2)2].
BENEFITS OF THE SOLUTION Possibility of obtaining parts that are lighter and cheaper than solid element with the desired properties (by depositing thin rhenium covers, on carbon material or other substrates)
AREA OF APPLICATION Electronics, electrical engineering, process engineering
TECHNOLOGICAL READINESS LEVEL 6
LINK TO THE OFFICE DATABASE https://ewyszukiwarka.pue.uprp.gov.pl/search/pwp-details/P.442616